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An atom such as chlorine has both a covalent radius (the distance between the two atoms in a Cl2 C l 2 molecule) and a van der Waals radius (the distance between two Cl atoms in different molecules in, for example, Cl2(s) C l 2 ( s) at low temperatures). These radii are generally not the same (part (d) in Figure 2.8.2).

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