Minerals in shale.

Hard minerals in granite can bear high stresses and promote the fracture surfaces overriding each other (Jia et al. 2020b), while soft minerals in shale can be compacted and densified to restrict fluid flow (Gutierrez et al. 2000). The permeability enhancement more likely occurs on the rough fractures (e.g., cases 5 and 6), and the …Sep 1, 2018 · Constraining mineral abundances is particularly difficult in shale due to preferred mounting orientation of common phyllosilicate phases, commonly leading to overestimation of clay minerals and mica. We introduce a quantitative approach to constraining mineralogy within mudrock by integrating x-ray diffraction (XRD) and x-ray fluorescence (XRF ... The paleoenvironment, mineral composition, elements and reservoir characteristics of black shale of the Lower Silurian Longmaxi formation southeast of Chongqing ...The ultimate recovery of shale oil is mostly dependent upon the occurrence and content of free oil within the nano-scaled pore network of shale reservoirs. Due to the nanoporous nature of shale, quantitatively characterizing the occurrence and content of free oil in shale is a formidable undertaking. To tackle this challenge, 12 lacustrine shale samples with …The geochemical reaction between ScCO 2-water and shale is the main reason for the change of mineral composition in shale. The dissolution in shale minerals by ScCO 2-water will be enhanced with the increasing soak pressure and weakened with the increasing soak temperature, and different minerals show different reaction behaviors with ScCO 2-water.

The majority of the IR bands that appear in the mid-infrared region between 4000 to 400 cm −1 are due to mineral/inorganic components. A number of weak bands attributed to organic components in the shale rock were observed from 3000 to 2800 cm −1 and these will be discussed in more detail later.Wellbore instability is one of the major problems associated with shale formations during drilling activities especially in the presence of active clay minerals ( Rana et al., 2020 ).The viscoelastic behavior of minerals in shales is important in predicting the macroscale creep behavior of heterogeneous bulk shale. In this study, in situ indentation measurements of two major constitutive minerals (i.e., quartz and clay) in Longmaxi Formation shale from the Sichuan Basin, South China, were conducted using a nanoindentation technique and high-resolution optical microscope.

Shale is a lithified mud — a sedimentary rock composed mostly of clay- and silt-sized grains. There are several ways to define shale. Some definitions are rather narrow. Glossary of Geology published by the American Geological Institute defines shale as a laminated, indurated rock with >67% clay-sized minerals 1.

Based on statistical analyses, positive correlation relationships were found between water absorption capacity and clay mineral contents for both groups of investigated shale samples under different water pressure (Table 9.4). These results indicate that the clay minerals, specifically illite in this case, play an important role in water absorption …The mineral content of the shale samples collected at the same sampling site was similar within a certain range. Taken together, these results show that the shale mineral content is closely related to the sedimentary source. Download : Download high-res image (627KB) Download : Download full-size image; Fig. 3. Mineral compositions and …Jan 1, 2022 · In this study, the effects of organic matter, clay minerals and organo-clay composites on pore structure and pore complexity of marine Longmaxi shale (LMX shale) and continental Ziliujing shale (ZLJ shale) were investigated qualitatively and quantitatively by field emission scanning electron microscopy (FE-SEM), N 2 adsorption experiment with ... Jul 12, 2022 · The microstructure of shale reservoirs refers to the distribution of mineral–organic matter, pore–fracture features, diagenetic processes, and their interrelations. The comprehensive and accurate analysis of the shale microstructure plays a critical role in formulating a reasonable development plan and optimizing measures to enhance oil or gas recovery. To explore the microstructure ... Hydrocarbons that are transported in a hierarchal path from the nanoporous constituents of a shale matrix to natural and then hydraulic fractures are subject to continuous fractionation during the journey. The organic nanopores of a source rock matrix known as kerogen have pore sizes on the angstrom scale. At that degree of confinement, …

Rocks and minerals can be easily identified once you know what to look for. There are three different types of rocks: Igneous, Metamorphic and Sedimentary. Minerals must meet several requirements, including being naturally occurring and ino...

Jan 13, 2022 · The Longmaxi Formation shale is a fine-grained sedimentary rock composed mainly of large amounts of brittle minerals, such as quartz and abundant clay minerals (≥75 vol.%; [24–26]).

Shale is featured by nanometer pores and ultralow permeability. Enhancing shale oil recovery after primary production is challenging as a result of the low injectivity of water. CO2 could be a promising injection fluid to enhance shale oil recovery for its high mobility in porous media and mixability with hydrocarbons. Fluid behaviors in the nanometer pores of shale reservoirs deviate from ...May 31, 2023 · In addition to inorganic minerals, shale also contains a certain amount of organic matter. Based on the molecular structure of kerogen in the studied shales, the kerogen slit model was established using the excision method, as detailed in Ref. . To clarify the adsorption discrepancies between inorganic minerals and organic matter in shale, the ... Twelve representative samples were collected from the shale beds of the El-Beida and Nakheil mines in the south part of the Qusseir. Four selected samples were investigated mineralogically by the X-ray technique at the Egyptian Mineral Resources Authority (Dokki, Egypt) using a PAN analytical X-ray Diffraction device, model X’Pert PRO with Secondary Monochromator.Shale is a lithified mud — a sedimentary rock composed mostly of clay- and silt-sized grains. There are several ways to define shale. Some definitions are rather narrow. Glossary of Geology published by the American Geological Institute defines shale as a laminated, indurated rock with >67% clay-sized minerals 1. Detrital minerals can also be adsorbed on the surface of bacterial cells . Fossilized bacteria have not been identified in association with Burgess Shale fossils, but this does not eliminate a role for microorganisms in the preservation process. They may not have been preserved, or they may have been obliterated during later diagenesis .

May 30, 2019 · Meanwhile, clay minerals have gone through mineral transformation and orientational evolution. The interaction of the two processes makes a significant difference to the microstructure evolution of OM and clay minerals in shale, and the findings provide scientific foundation in better understanding diagenetic evolution and hydrocarbon ... Shale forms from the pressure of layers of sediment compressing bits of silt that settle into the clay on the bottom of bodies of water. The compressed clay and silt become shale over time. Shale is a sedimentary rock.Shale is featured by nanometer pores and ultralow permeability. Enhancing shale oil recovery after primary production is challenging as a result of the low injectivity …Nov 1, 2016 · The mineral composition plays a significant role, followed by the mechanical properties and mineral/organic carbon content of the shale, abnormal pressures (including fluid over-pressure effects), shale thickness, dehydration and ductile properties of the clay minerals, compaction and pressure solution during shale diagenesis, thermal shrinkage ... Fig. 1 shows the X-ray diffraction (XRD) results of shale samples, and the main minerals are 20.5% quartz, 12.3% kaolinite, 25.2% illite, and 42.0% anorthite, respectively. In addition, most of the schistose minerals in shale samples are stacked and the overall structure is relatively dense, but there are still some microcracks and micropores ...Cannel shale has terrestrial origins, and is often classified as coal. It is made up from the remains of resin, spores, and corky materials from woody plants. It can contain the minerals inertinite and vitrinite. Cannel shale is rich in hydrogen, and burns easily. Using Oil Shale. People have been using oil shale for thousands of years.Science Issue and Relevance Black shales have been of increasing interest in recent years due to their oil and gas potential, but also because many are enriched in nonfuel "unconventional" critical elements such as cobalt, chromium, molybdenum, nickel, platinum group elements, rhenium, and vanadium.

Esfand 8, 1401 AP ... The inorganic minerals commonly found in shale, namely calcite (1 0 0), quartz (0 0 1) and clay minerals (illite) (0 0 1), were used for the ...

Hydrocarbons that are transported in a hierarchal path from the nanoporous constituents of a shale matrix to natural and then hydraulic fractures are subject to continuous fractionation during the journey. The organic nanopores of a source rock matrix known as kerogen have pore sizes on the angstrom scale. At that degree of confinement, …Dey 18, 1394 AP ... 4. Composition of Shale Composed mainly of clay-size mineral grains. Tiny grains are usually clay minerals such as illite , kaolinite and ...Nov 1, 2020 · The Brachina Formation shows a similar type of detrital mineral assemblage to the Enorama Shale, but with differing abundance and grain size. Detrital phases include quartz, K-feldspar, albite, mica, 2M 1 illite, chlorite, and a small quantity of rutile and apatite. The detrital grain size in this formation varies in each lamina (Fig. 6 a). The ... Shale is composed of mineral and fracture system. (b) Main controlling factors of stress concentration under different mineral content. (c) Main controlling factors of stress under different fracture development degrees. (d) Comparison of effect of shale microscopic characteristics on stress concentration. The effect of fractures on stress values is related …Density and minerology of shale. Before the treatment test, the density in g/cm 3 of each shale was measured and found 2.29 for Opalinus, 2.53 for Haynesville, 2.58 for Longmaxi, and 2.43 for ...Twelve representative samples were collected from the shale beds of the El-Beida and Nakheil mines in the south part of the Qusseir. Four selected samples were investigated mineralogically by the X-ray technique at the Egyptian Mineral Resources Authority (Dokki, Egypt) using a PAN analytical X-ray Diffraction device, model X’Pert PRO with Secondary Monochromator.Nano-scale pores play an important role in determining the adsorption capacity of shale gas. To quantitatively evaluate the pore size distributions contributed by organic matter (OM), clay and other minerals in an over-mature shale reservoir, the Lower Silurian Longmaxi shale from Southeast Chongqing was selected as a case study and was analyzed by the pore size distributions contributed by OM ...Mehr 8, 1397 AP ... Oil shale mineral from Belarus on white background potentially for economic news on fuel and energy markets prices Stock illustration ...Aug 15, 2023 · Shale reservoirs often undergo intense clay mineral transformation, which plays a crucial role in the formation and evolution of pores. The reservoir lithofacies types of Da’anzhai Member in the Sichuan Basin are complex, the heterogeneity is strong, and the transformation mechanism of clay minerals is unclear, limiting the understanding of reservoir diagenesis and reservoir formation mechanism. Shale mineral particle sizes are generally between 3.2 and 35 μm (Lei et al., 2015). Considering that the calculation speed was improved without affecting the accuracy of the model when building the numerical model, the pixels of FIB-SEM images were reduced by two times, and one image was read at each interval. That is, the image spacing was …

Compared with the marine shale in China, the TOC and carbonate mineral contents are considerably higher in the Es4s–Es3x rocks [57–60]. Moreover, compared with some major shale in the United States, the Es4s–Es3x shale has deep burial depth, low thermal maturity, high carbonate content, and low quartz content.

The mineral composition of rocks in shale is an important factor affecting wettability (Barclay and Worden, 2000). Different mineral surfaces have different adsorption effects on polar compounds, so they may have different wettability characteristics (Xi et al., 2019).

1. Introduction. Shale comprises a heterogeneous and typically laminated fine-grained assemblage of minerals imparting both strong anisotropy and low permeability (Ma et al., 2016, Ougier-Simonin et al., 2016, Anastasia et al., 2017, Li et al., 2019, Zou et al., 2019).Such strong heterogeneity and anisotropy in mechanical and transport properties …Bentonite layers from an ancient deposit of weathered volcanic ash tuff in Wyoming Gray shale and bentonites (Benton Shale; Colorado Springs, Colorado). Bentonite (/ ˈ b ɛ n t ə n aɪ t /) is an absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite.Na-montmorillonite has a …During thermal evolution, the clay minerals in the shale will dehydrate, and then undergo conversion and dissolve, which will cause the pore characteristics of the shale to change. XRD can be used to quantitatively characterize the clay and other rigid mineral contents in shale (Houben et al. 2016 ).The paleoenvironment, mineral composition, elements and reservoir characteristics of black shale of the Lower Silurian Longmaxi formation southeast of Chongqing ...Sep 4, 2019 · Shale lithics contain silt-sized minerals (mostly quartz) scattered in a clay mineral-dominated matrix (Figure 8C,D). The clays in shale lithics are characterized by a more wavy-planar fabric (Figure 8 D), compared with the highly crenulated morphology of smectite in bentonites and volcanic rock fragments. In this study, the effects of organic matter, clay minerals and organo-clay composites on pore structure and pore complexity of marine Longmaxi shale (LMX shale) and continental Ziliujing shale (ZLJ shale) were investigated qualitatively and quantitatively by field emission scanning electron microscopy (FE-SEM), N 2 adsorption experiment with ...Therefore, in this study, we conducted nanoscopic modeling of shale nanocomposites, wherein one surface consists of type II-C kerogen and the other surface is composed of K-illite minerals. We aim to investigate the influence of water content, temperature, pressure, pore width, and rigid/flexibility of the kerogen matrix on the adsorption capacity of CH 4 in …Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons can be produced. ... The mineral matter in oil shale includes various fine-grained silicates and carbonates. Inorganic matrix can contain quartz, feldspar, clay (mainly illite and chlorite), carbonate …

Organic matter and clay minerals have different effects on shale pore structure and pore complexity of marine shale and continental shale. Organic matter …Apr 1, 2014 · Where smectite is a major or significant clay component of a shale, as in Classes 1 and 2, then the shale instability can be readily rationalized in terms of the well known swelling behaviour of the smectite minerals in water and when saturated with different cations (Mooney et al., 1952; Norrish, 1954). Mar 1, 2022 · The alterations of the mechanical properties of shale matrix minerals can provide insights into the compressibility of fracture networks and the evolutionary laws of shale's micromechanical properties, and then revealing the inner weakening mechanisms of shale's macro-mechanical properties in the process of ScCO 2 fracturing and CO 2-enhanced ... Instagram:https://instagram. citing patentseuler circuit definitionbakugou katsuki ao3education specialist degree in school psychology Siliceous minerals are positively correlated with water-wet. Carbonate and clay minerals are negatively correlated with water-wet. The mineralogical composition of the shale, the composition of the oil, the characteristics of the aqueous media, the asphaltene deposits on the surface, temperature, and pressure all impact wettability.Shale is an important self-sourced reservoir rock in many sedimentary basins worldwide. In this research work, a geochemical history of variations in the sedimentary environment of the lacustrine basin is analyzed based on extensive shale samples collected from the lower 3rd member (Es 3 L) and upper 4th member (Es 4 U) of the Paleogene … e'shee nails spa reviewspaises de guatemala Siliceous minerals are positively correlated with water-wet. Carbonate and clay minerals are negatively correlated with water-wet. The mineralogical composition of the shale, the composition of the oil, the characteristics of the aqueous media, the asphaltene deposits on the surface, temperature, and pressure all impact wettability. keenan eaton Wellbore instability is one of the major problems associated with shale formations during drilling activities especially in the presence of active clay minerals ( Rana et al., 2020 ).Type Sedimentary Rock Origin Detrital/Clastic Texture Clastic; Very fine-grained (< 0.004 mm) Composition Clay minerals, Quartz Color Brown Miscellaneous Blocky Depositional Environment Flood Plain, Lake (away from shore), Mid-continental Shelf, Delta, Tidal Flat, Lagoon, or Deep Marine Type Sedimentary Rock Origin Detrital/Clastic Texture Clastic; Very fine-grained (< 0.004 mm) Composition ...The mechanical properties of the constituent minerals in shale rock are fundamental to a better knowledge of multi-scale shale behaviors. It benefits the …